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Assesment of technical lignins for uses in biofuels and biomaterials: Structure-related properties, proximate analysis and chemical modification
University of the Basque Country, Donostia-San Sebastián, Spain.
KTH Royal Institute of technology.ORCID-id: 0000-0002-0252-337X
KTH Royal Institute of technology.
University of the Basque Country, Donostia-San Sebastián, Spain.
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2016 (Engelska)Ingår i: Industrial crops and products (Print), ISSN 0926-6690, E-ISSN 1872-633X, Vol. 83, s. 155-165Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

The potential of organosolv and kraft eucalyptus and spruce lignin as feedstock for polymeric materials and biofuel applications was assessed. Proximate analysis was used to predict the heating values and char formation. Chemical modification, based on the esterification reaction with methacryloyl chloride, was applied to introduce vinyl groups into the lignin macromolecules for enhanced reactivity. Kraft eucalyptus and spruce lignins had a more condensed structure than organosolv lignins, which resulted in greater thermal stability for these lignins. For different species within the same process, the thermal parameters showed a correlation with certain structural and compositional parameters (ash and sugars content, molecular weight and degree of condensation). Organosolv spruce lignin produced the highest heating value of 24. MJ/Kg, which is suitable for biofuel applications. The content of phenolic OH groups was higher for kraft lignins and especially higher for softwood lignins, both organosolv and kraft. The degree of methacrylation, estimated from the content of vinyl groups per C9 lignin unit, was significantly greater for organosolv lignins than for kraft lignins despite the higher OH-groups content in the latter.

Ort, förlag, år, upplaga, sidor
2016. Vol. 83, s. 155-165
Nyckelord [en]
Functional groups, Kraft, Lignin methacrylates, Organosolv, Proximate analysis
Nationell ämneskategori
Trävetenskap
Identifikatorer
URN: urn:nbn:se:his:diva-15856DOI: 10.1016/j.indcrop.2015.12.048ISI: 000370894000022Scopus ID: 2-s2.0-84952892733OAI: oai:DiVA.org:his-15856DiVA, id: diva2:1228741
Tillgänglig från: 2016-02-01 Skapad: 2018-06-28 Senast uppdaterad: 2018-08-14Bibliografiskt granskad

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